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As the [[buoyancy pressure]] increases with height above the free-water level, the oil phase will displace more water from increasingly smaller pore volumes. The effect of this is that hydrocarbon saturations increase with height above the [[Fluid contacts|hydrocarbon-water contact]]. The relationship between capillary and buoyancy forces thus controls the static distribution of fluids in oil and gas pools. Knowledge of these relationships is fundamental to the accurate calculation of hydrocarbon volumes within a reservoir.
 
As the [[buoyancy pressure]] increases with height above the free-water level, the oil phase will displace more water from increasingly smaller pore volumes. The effect of this is that hydrocarbon saturations increase with height above the [[Fluid contacts|hydrocarbon-water contact]]. The relationship between capillary and buoyancy forces thus controls the static distribution of fluids in oil and gas pools. Knowledge of these relationships is fundamental to the accurate calculation of hydrocarbon volumes within a reservoir.
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Capillary pressure is typically measured in the laboratory by injecting mercury under pressure into a core plug. The mercury is a nonwetting phase, which replicates the behavior of hydrocarbons in reservoir rocks. The procedure simulates the entry of hydrocarbons into a water-wet rock and the way in which buoyancy pressure increases with height in the hydrocarbon column.
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Capillary pressure is typically measured in the laboratory by injecting mercury under pressure into a core plug. The mercury is a nonwetting phase, which replicates the behavior of hydrocarbons in reservoir rocks. The procedure simulates the entry of hydrocarbons into a water-wet rock and the way in which buoyancy pressure increases with height in the [[hydrocarbon column]].
    
Mercury will not enter the rock immediately. The pressure required to do this will depend on the radius of the pore throats, the contact angle, and the mercury-air interfacial tension. The pressure at which the mercury effectively enters the pore network is termed the displacement or entry pressure.<ref name=Vavra1992 /> Lower entry pressures are found in the better quality reservoir rocks, that is, those with larger pore throat diameters. A cap rock with tiny capillaries, shale for instance, has a very high [[displacement pressure]]. The displacement pressure for a [http://www.oxforddictionaries.com/us/definition/american_english/cap-rock cap rock] can be so high that the tightly bound water in the pore space of the shale will prevent the oil from entering and the oil remains trapped in the underlying reservoir rock.<ref name=Berg1975>Berg, R. R., 1975, [http://archives.datapages.com/data/bulletns/1974-76/data/pg/0059/0006/0900/0939.htm Capillary pressures in stratigraphic traps]: AAPG Bulletin, v. 59, no. 6, p. 939–956.</ref><ref name=Schowalter1979 />
 
Mercury will not enter the rock immediately. The pressure required to do this will depend on the radius of the pore throats, the contact angle, and the mercury-air interfacial tension. The pressure at which the mercury effectively enters the pore network is termed the displacement or entry pressure.<ref name=Vavra1992 /> Lower entry pressures are found in the better quality reservoir rocks, that is, those with larger pore throat diameters. A cap rock with tiny capillaries, shale for instance, has a very high [[displacement pressure]]. The displacement pressure for a [http://www.oxforddictionaries.com/us/definition/american_english/cap-rock cap rock] can be so high that the tightly bound water in the pore space of the shale will prevent the oil from entering and the oil remains trapped in the underlying reservoir rock.<ref name=Berg1975>Berg, R. R., 1975, [http://archives.datapages.com/data/bulletns/1974-76/data/pg/0059/0006/0900/0939.htm Capillary pressures in stratigraphic traps]: AAPG Bulletin, v. 59, no. 6, p. 939–956.</ref><ref name=Schowalter1979 />

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