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When hydrocarbons migrate into a trap, the buoyancy force exerted by the lighter oil (or gas) will push the water that was previously in the pore space sideways and downward. However, not all of the water is displaced; some of it will be held by capillary forces within the pores. Narrower capillaries, pores with smaller pore throats, hold onto water the strongest.
 
When hydrocarbons migrate into a trap, the buoyancy force exerted by the lighter oil (or gas) will push the water that was previously in the pore space sideways and downward. However, not all of the water is displaced; some of it will be held by capillary forces within the pores. Narrower capillaries, pores with smaller pore throats, hold onto water the strongest.
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The two forces acting on the fluids in the pore space are controlled by physical laws. The equation for the buoyancy pressure is given by
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The two forces acting on the fluids in the pore space are controlled by physical laws. The equation for the [[buoyancy pressure]] is given by
    
:<math>P_b = (\rho_w - \rho_{nw})gh</math>
 
:<math>P_b = (\rho_w - \rho_{nw})gh</math>
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For an oil field, the capillary-bound water comprises a continuous column of water within the oil leg, which will have a hydrostatic pressure gradient controlled by the water density. The oil is located in the remaining pore space as a continuous phase and will have a pressure gradient controlled by the (lower) oil density ([[:file:Mem91BuoyancyForcesFig26.jpg|Figure 1]]). Although oil and water can coexist in the same localized volume of rock, the pressures acting on the two fluids are different. The difference in pressure between the oil and water phases increases with height above the free-water level. The free-water level is the level at which the water-hydrocarbon interface would theoretically stand in a large open hole drilled through the oil column.<ref name=Schowalter1979>Schowalter, T. T., 1979, [http://archives.datapages.com/data/bulletns/1977-79/data/pg/0063/0005/0700/0723.htm Mechanics of secondary hydrocarbon migration and entrapment]: AAPG Bulletin, v. 63, no. 5, p. 723–760.</ref> In this situation, only gravity and buoyancy forces control the fluid distribution in the borehole.
 
For an oil field, the capillary-bound water comprises a continuous column of water within the oil leg, which will have a hydrostatic pressure gradient controlled by the water density. The oil is located in the remaining pore space as a continuous phase and will have a pressure gradient controlled by the (lower) oil density ([[:file:Mem91BuoyancyForcesFig26.jpg|Figure 1]]). Although oil and water can coexist in the same localized volume of rock, the pressures acting on the two fluids are different. The difference in pressure between the oil and water phases increases with height above the free-water level. The free-water level is the level at which the water-hydrocarbon interface would theoretically stand in a large open hole drilled through the oil column.<ref name=Schowalter1979>Schowalter, T. T., 1979, [http://archives.datapages.com/data/bulletns/1977-79/data/pg/0063/0005/0700/0723.htm Mechanics of secondary hydrocarbon migration and entrapment]: AAPG Bulletin, v. 63, no. 5, p. 723–760.</ref> In this situation, only gravity and buoyancy forces control the fluid distribution in the borehole.
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As the buoyancy pressure increases with height above the free-water level, the oil phase will displace more water from increasingly smaller pore volumes. The effect of this is that hydrocarbon saturations increase with height above the [[Fluid contacts|hydrocarbon-water contact]]. The relationship between capillary and buoyancy forces thus controls the static distribution of fluids in oil and gas pools. Knowledge of these relationships is fundamental to the accurate calculation of hydrocarbon volumes within a reservoir.
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As the [[buoyancy pressure]] increases with height above the free-water level, the oil phase will displace more water from increasingly smaller pore volumes. The effect of this is that hydrocarbon saturations increase with height above the [[Fluid contacts|hydrocarbon-water contact]]. The relationship between capillary and buoyancy forces thus controls the static distribution of fluids in oil and gas pools. Knowledge of these relationships is fundamental to the accurate calculation of hydrocarbon volumes within a reservoir.
    
Capillary pressure is typically measured in the laboratory by injecting mercury under pressure into a core plug. The mercury is a nonwetting phase, which replicates the behavior of hydrocarbons in reservoir rocks. The procedure simulates the entry of hydrocarbons into a water-wet rock and the way in which buoyancy pressure increases with height in the hydrocarbon column.
 
Capillary pressure is typically measured in the laboratory by injecting mercury under pressure into a core plug. The mercury is a nonwetting phase, which replicates the behavior of hydrocarbons in reservoir rocks. The procedure simulates the entry of hydrocarbons into a water-wet rock and the way in which buoyancy pressure increases with height in the hydrocarbon column.

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