| In Sweden and Denmark, the Skegerrak-Kattegat Basin contains the Cambrian–Ordovician Alum Shale, which has also been studied extensively.<ref>Lewan, M. D., and B. Buchardt, 1989, Irradiation of organic matter by uranium decay in the Alum Shale, Sweden: Geochemica et Cosmochimica Acta, v. 53, p. 1307–1322, doi:10.1016/0016-7037(89)90065-3.</ref><ref>Bharati, S., R. L. Patience, S. R. Larter, G. Standen, and I. J. F. Poplett, 1995, Elucidation of the Alum Shale kerogen structure using a multidisciplinary approach: Organic Geochemistry, v. 23, no. 11–12, p. 1043–1058, doi:10.1016/0146-6380(95)00089-5.</ref><ref> Buchardt, B., A. Thorshoj Nielsen, and N. Hemmingsen Schovsbo, 1997, Alun Skiferen i Skandinavien, Dansk Geologisk Forenings Nyheds: OG Informationsskirft, 32 p.</ref>. The Alum Shale is organic rich, with high TOC (11–22%) and HIo, yet generates primarily gas and condensate upon thermal conversion.<ref>Horsfield, B., S. Bharati, S. R. Larter, F. Leistner, R. Littke, H. J. Schenk, and H. Dypvik, 1992, On the atypical petroleum-generating characteristics of alginate in the Cambrian Alum Shale, in M. Schidlowski, S. Golubic, M. M. Kimerly, and P. A. Trudinger, eds., Early organic evolution: Implications for mineral and energy resources: Berlin, Springer-Verlag, p. 257–266.</ref> Compositional yield data derived from immature Alum Shale with an HI of 487 mg HC/g TOC show that strictly primary kerogen and bitumen and/or oil cracking yields about 60% gas, quite unusual for source rocks of comparable HIo values that typically only yield 20 to 30% gas (D. M. Jarvie, unpublished data). Shell Oil Company has now drilled at least two wells into the Alum Shale, but no results are available. | | In Sweden and Denmark, the Skegerrak-Kattegat Basin contains the Cambrian–Ordovician Alum Shale, which has also been studied extensively.<ref>Lewan, M. D., and B. Buchardt, 1989, Irradiation of organic matter by uranium decay in the Alum Shale, Sweden: Geochemica et Cosmochimica Acta, v. 53, p. 1307–1322, doi:10.1016/0016-7037(89)90065-3.</ref><ref>Bharati, S., R. L. Patience, S. R. Larter, G. Standen, and I. J. F. Poplett, 1995, Elucidation of the Alum Shale kerogen structure using a multidisciplinary approach: Organic Geochemistry, v. 23, no. 11–12, p. 1043–1058, doi:10.1016/0146-6380(95)00089-5.</ref><ref> Buchardt, B., A. Thorshoj Nielsen, and N. Hemmingsen Schovsbo, 1997, Alun Skiferen i Skandinavien, Dansk Geologisk Forenings Nyheds: OG Informationsskirft, 32 p.</ref>. The Alum Shale is organic rich, with high TOC (11–22%) and HIo, yet generates primarily gas and condensate upon thermal conversion.<ref>Horsfield, B., S. Bharati, S. R. Larter, F. Leistner, R. Littke, H. J. Schenk, and H. Dypvik, 1992, On the atypical petroleum-generating characteristics of alginate in the Cambrian Alum Shale, in M. Schidlowski, S. Golubic, M. M. Kimerly, and P. A. Trudinger, eds., Early organic evolution: Implications for mineral and energy resources: Berlin, Springer-Verlag, p. 257–266.</ref> Compositional yield data derived from immature Alum Shale with an HI of 487 mg HC/g TOC show that strictly primary kerogen and bitumen and/or oil cracking yields about 60% gas, quite unusual for source rocks of comparable HIo values that typically only yield 20 to 30% gas (D. M. Jarvie, unpublished data). Shell Oil Company has now drilled at least two wells into the Alum Shale, but no results are available. |
− | Data from Poland suggest a variety of shale-gas potential in various basins such as the Baltic, Lublin, and Carpathian. Shale-gas resource potential exists in the Silurian Graptolitic Shale. Comparing data from across Poland using two criteria for shale-gas prospectivity, organic richness, and level of conversion, TOCpd values range from 2 to 18%, some with gas window levels of conversion (Figure 8). It is recently announced that the first shale stimulation in Europe has been completed on the 1-Markowolain well in the Lublin Basin. No gas flow data have been reported. | + | Data from Poland suggest a variety of shale-gas potential in various basins such as the Baltic, Lublin, and Carpathian. Shale-gas resource potential exists in the Silurian Graptolitic Shale. Comparing data from across Poland using two criteria for shale-gas prospectivity, organic richness, and level of conversion, TOCpd values range from 2 to 18%, some with gas window levels of conversion ([[:File:M97FG8.jpg|Figure 8]]). It is recently announced that the first shale stimulation in Europe has been completed on the 1-Markowolain well in the Lublin Basin. No gas flow data have been reported. |
− | Silurian–Devonian shales show good potential for shale-gas in Algeria and Tunisia (see Figure 8).<ref>Jarvie, D. M., R. J. Hill, R. M. Pollastro, D. A. Wavrek, K. A. Bowker, B. L. Claxton, and M. H. Tobey, 2005b, [http://wwgeochem.com/references/Jarvie-etal2005bcharacterizationofthermogenicgasandoilFtWorthBasinTexasEAGE-Algiers.pdf Characterization of thermogenic gas and oil in the Ft. Worth Basin, Texas]: European Association of Geoscientists and Engineers Meeting, Algiers, Algeria, April 8–10, 2005.</ref> In 2010, it was announced that the first stimulation of a potential shale-gas well was undertaken in the Ghadames Basin, west-central Tunisia, likely in the Silurian Tannezuft Shale.<ref>Oil & Gas Journal, 2010a, [http://www.ogj.com/index/article-tools-template/_printArticle/articles/oil-gas-journal/drilling-production-2/2010/08/north-africa_gets.html North Africa gets first shale gas frac job], August 30, 2010.</ref> | + | Silurian–Devonian shales show good potential for shale-gas in Algeria and Tunisia (see [[:File:M97FG8.jpg|Figure 8]]).<ref>Jarvie, D. M., R. J. Hill, R. M. Pollastro, D. A. Wavrek, K. A. Bowker, B. L. Claxton, and M. H. Tobey, 2005b, [http://wwgeochem.com/references/Jarvie-etal2005bcharacterizationofthermogenicgasandoilFtWorthBasinTexasEAGE-Algiers.pdf Characterization of thermogenic gas and oil in the Ft. Worth Basin, Texas]: European Association of Geoscientists and Engineers Meeting, Algiers, Algeria, April 8–10, 2005.</ref> In 2010, it was announced that the first stimulation of a potential shale-gas well was undertaken in the Ghadames Basin, west-central Tunisia, likely in the Silurian Tannezuft Shale.<ref>Oil & Gas Journal, 2010a, [http://www.ogj.com/index/article-tools-template/_printArticle/articles/oil-gas-journal/drilling-production-2/2010/08/north-africa_gets.html North Africa gets first shale gas frac job], August 30, 2010.</ref> |
| In South Africa, the Karoo Basin is being evaluated for its shale-gas potential by various companies<ref>Oil & Gas Journal, 2010b, [http://www.ogj.com/index/article-tools-template.articles.oil-gas-journal.exploration-development-2.2010.07.south-africa_karoo.html South Africa Karoo shale gas hunt growing].</ref> with various conventional and unconventional opportunities.<ref>Raseroka, L., and I. R. McLachlan, 2009, [http://www.searchanddiscovery.net/documents/2009/10196raseroka/index.htm?q=%2Btext%3Araseroka The petroleum potential of South Africa's onshore Karoo basins (abs.)]: AAPG International Conference and Exhibition, Cape Town, South Africa, October 26–29, 2008, Search and Discovery Article 10196, 3 p.</ref> | | In South Africa, the Karoo Basin is being evaluated for its shale-gas potential by various companies<ref>Oil & Gas Journal, 2010b, [http://www.ogj.com/index/article-tools-template.articles.oil-gas-journal.exploration-development-2.2010.07.south-africa_karoo.html South Africa Karoo shale gas hunt growing].</ref> with various conventional and unconventional opportunities.<ref>Raseroka, L., and I. R. McLachlan, 2009, [http://www.searchanddiscovery.net/documents/2009/10196raseroka/index.htm?q=%2Btext%3Araseroka The petroleum potential of South Africa's onshore Karoo basins (abs.)]: AAPG International Conference and Exhibition, Cape Town, South Africa, October 26–29, 2008, Search and Discovery Article 10196, 3 p.</ref> |