| Carbon dioxide, hydrogen sulfide, and nitrogen can constitute a significant percentage of natural gas from some accumulations. In some cases, natural gas is uneconomic due to the high nonhydrocarbon gas content. | | Carbon dioxide, hydrogen sulfide, and nitrogen can constitute a significant percentage of natural gas from some accumulations. In some cases, natural gas is uneconomic due to the high nonhydrocarbon gas content. |
− | Although low concentrations of carbon dioxide can be derived from organic sources or byproducts of silicate reactions at moderate temperatures<ref name=ch11r32>Smith, J., T., Ehrenberg, S., N., 1989, Correlation of carbon dioxide abundance with temperature in clastic hydrocarbon reservoirs: relationship to inorganic chemical equilibrium: Marine and Petroleum Geology, vol. 6, p. 129–135., 10., 1016/0264-8172(89)90016-0</ref> high concentrations of carbon dioxide are usually associated with igneous intrusion or regional heating of impure limestones.<ref name=ch11r9>Farmer, R., E., 1965, Genesis of subsurface carbon dioxide, in Young, A., Galley, J., eds., Fluids in Subsurface Environments: AAPG Memoir No. 4, p. 378–385.</ref> | + | Although low concentrations of carbon dioxide can be derived from organic sources or byproducts of silicate reactions at moderate temperatures<ref name=ch11r32>Smith, J., T., Ehrenberg, S., N., 1989, Correlation of carbon dioxide abundance with temperature in clastic hydrocarbon reservoirs: relationship to inorganic chemical equilibrium: Marine and Petroleum Geology, vol. 6, p. 129–135., 10., 1016/0264-8172(89)90016-0</ref> high concentrations of carbon dioxide are usually associated with igneous intrusion or regional heating of impure limestones.<ref name=ch11r9>Farmer, R., E., 1965, [http://archives.datapages.com/data/specpubs/methodo2/data/a071/a071/0001/0350/0378.htm Genesis of subsurface carbon dioxide], in Young, A., Galley, J., eds., Fluids in Subsurface Environments: AAPG Memoir No. 4, p. 378–385.</ref> |
| Hydrogen sulfide concentration increases with depth in gas reservoirs with anhydrite, indicating that it, too, is a product of higher maturity.<ref name=ch11r20 />). The methane is reacting with the sulfate to form hydrogen sulfide and carbon dioxide gas. The reaction is probably kinetically controlled. | | Hydrogen sulfide concentration increases with depth in gas reservoirs with anhydrite, indicating that it, too, is a product of higher maturity.<ref name=ch11r20 />). The methane is reacting with the sulfate to form hydrogen sulfide and carbon dioxide gas. The reaction is probably kinetically controlled. |