Stable isotope stratigraphy

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Exploring for Oil and Gas Traps
Series Treatise in Petroleum Geology
Part Predicting the occurrence of oil and gas traps
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Author Robert L. Fleisher, H. Richard Lane
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The shells of some carbonate-secreting marine organisms reflect the isotopic composition of the seawater in which they live. Technical advances in micromass spectrometry and the advent of deep-ocean hydraulic piston coring have permitted, through analysis of fossil carbonate shells, a rapid, cost-effective, and precise estimation of the isotopic composition of seawater through geologic time.

Isotopic correlation

Comparison of curves representing isotopic values through time can provide a basis for regional or even worldwide correlations. Although biotic and diagenetic effects must be considered when evaluating and using isotopic data, isotopic techniques can significantly augment the resolution of existing biostratigraphic zonations and provide accurate correlations within basins. Two useful stable isotopic techniques involve measuring the ratios of isotopes of oxygen (18O/16O) and strontium (87Sr/86Sr).

Oxygen isotope model

Glacial-interglacial climatic fluctuations during the late Paleogene and Neogene have been causally related to Milankovitch orbital parameters (eccentricity, obliquity, and precession). During colder glacial climates the oceans become enriched in 18O relative to 16O because the lighter 16O molecule is more easily evaporated from seawater and becomes locked on land in the form of ice. During warmer intervals the reverse is true.

Figure 1 illustrates a typical oxygen isotope record (expressed as delta oxygen-18 values) for the middle Tertiary, showing standard Oligocene and Miocene isotope stages.

This record is for the middle Tertiary and shows standard Oligocene and Miocene isotope stages (Oi 1 = Oligocene isotope stage 1; Mi 1 = Miocene isotope stage 1; etc.). Oxygen isotope data are based on analyses of benthic foraminifera recovered from cores taken at seven Atlantic and Southern Ocean sites of the Ocean Drilling Program. The curve has been fitted through the data using statistical filter and smoothing techniques.

Oxygen isotope correlation

Statistical stacking of detailed records of oceanic 18O/16O ratios, based primarily on the analysis of foraminifera from numerous deep-ocean cores and calibration to the geologic time scale, lets us construct standard oxygen isotope chronologies for the Pliocene-Pleistocene.[4][5] and the Miocene and Oligocene[1]. Thus the oceanic 18O/16O record provides a precise correlative tool based on worldwide fluctuations in climate. Isotopic analysis of well-preserved foraminifera from core or outcrop samples or from well cuttings in areas of relatively high sedimentation rate may help us recognize worldwide oxygen isotope stages. Isotope studies can be useful locally in enhancing the stratigraphic resolution of existing biostratigraphy.

Figure 2 shows correlation of a Pleistocene section between two wells in the offshore Gulf of Mexico using bio stratigraphic control and the identification of standard oxygen isotope stages.

Strontium isotope stratigraphy

An extensive database of 87Sr/86Sr measurements on marine carbonate, evaporite, and phosphate samples compiled at Mobil and elsewhere has permitted construction of a 87Sr/86Sr “curve” for the Phanerozoic (see illustration below). During intervals when the 87Sr/86Sr curve is relatively linear and steep with respect to time (e.g., during the Permian, Jurassic, Late Cretaceous, and several intervals within the Late Eocene to Holocene), the strontium curve can be used as a chronometer because any given ratio along the line can be associated with a unique numerical age. The accuracy of the resulting age estimates approaches ±1.0 m.y for the Cenozoic intervals.

Figure 3 shows evolution of the 87Sr/86Sr ratio in seawater through the Phanerozoic.

High-latitude example

The strontium isotope technique is especially useful in high-latitude and shallow-water marine sections of middle to late Tertiary age where biostratigraphic zones have relatively long durations and diagnostic calcareous taxa are often absent or difficult to identify.

Figure 4 shows 87Sr/86Sr age estimates based on isotopic analysis of fossil calcareous shell material for a section of a high-latitude exploration well. Age estimates for each sample represent the mean of ages derived using the 87Sr/86Sr age relationships of DePaolo and Ingram[7] Kopenick et al.[8] and DePaolo.[9] Analytical error associated with each data point yields age estimate errors of approximately ±1.0 m.y.

See also

References

  1. 1.0 1.1 Wright, J. D., and K. G. Miller, 1993, Southern Ocean influences on late Eocene to Miocene deep-water circulation: American Geophysical Union Antarctic Research Series, vol. 60, p. 1–25.
  2. 2.0 2.1 Berggren, W., A., Kent, D., V., Flynn, J., J., 1985a, Paleogene geochronology and chronostratigraphy, in Snelling, N., J., ed., The Chronology of the Geological Record: Geological Society of London Memoir 10, p. 141–195.
  3. Berggren, W., A., Kent, D., and J.A. van Couvering, 1985b, Neogene geochronology and chronostratig- raphy, in N.J. Snelling, ed., The Chronology of the Geological Record: Geological Society of London Memoir 10, p. 211–260.
  4. 4.0 4.1 Ruddiman, W. F., Raymo, M. E., Martinson, D. G., Clement, B. M., Backman, J., 1989, Pleistocene evolution: Northern Hemisphere ice sheets and North Atlantic Ocean: Paleoceanography, vol. 4, p. 353–412., 10., 1029/PA004i004p00353
  5. Shackleton, N. J., Berger, A., Peltier, W. R., 1990, An alternate astronomical calibration of the lower Pleistocene time scale based on Ocean Drilling Program Site 677: Transactions of the Royal Society of Edinburgh, Earth Sciences, vol. 81, p. 251–261., 10., 1017/S0263593300020782
  6. Burke, W., R., Denison, R., E., Hetherington, E., A., Koepnick, R., B., Nelson, H., F., Otto, J., B., 1982, Variation of seawater 87Sr/86Sr throughout Phanerozoic time: Geology, vol. 10, p. 516–519., 10., 1130/0091-7613(1982)10<516:VOSSTP>2., 0., CO;2
  7. DePaolo, D., J., Ingram, B., L., 1985, High-resolution stratigraphy with strontium isotopes: Science, vol. 227, p. 938–941., 10., 1126/science., 227., 4689., 938
  8. Kopenick, R., B., Burke, W., H., Denison, R., E., Hetherington, E., A., Nelson, H., F., Otto, J., B., Waite, L., E., 1985, Construction of the seawater 87Sr/86Sr curve for the Cenozoic and Cretaceous: supporting data: Chemical Geology (Isotope Geoscience Section), vol. 58, p. 55–81., 10., 1016/0168-9622(85)90027-2
  9. DePaolo, D., J., 1986, Detailed record of the Neogene Sr isotopic evolution of seawater from DSDP Site 590B: Geology, vol. 14, p. 103–106., 10., 1130/0091-7613(1986)14<103:DROTNS>2., 0., CO;2

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