Measuring displacement pressure using mercury injection

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Exploring for Oil and Gas Traps
Series Treatise in Petroleum Geology
Part Predicting the occurrence of oil and gas traps
Chapter Evaluating top and fault seal
Author Grant M. Skerlec
Link Web page
Store AAPG Store

The displacement pressure (Pd) is routinely inferred by forcing mercury into the pore space of a sample (cores or cuttings) and measuring the percent of mercury saturation vs. increasing pressure.

Procedure

Figure 1 Typical mercury capillary curve for a sandstone.[1]

Figure 1 shows a typical mercury capillary curve for a sandstone. Mercury is first forced into the largest connected pore throats. Saturation increases with increasing pressure as mercury continues to be forced into progressively smaller pore throats.

Values of displacement pressure>

Figure 2 Chart showing range of seal capacities for the different facies. Data from Vavra et al.[2]

Displacement pressure (Pd) is defined as the pressure necessary to form a continuous hydrocarbon filament in the pore space of the seal. It is commonly inferred from the injection pressure at 10% saturation[1] for two reasons:

  • Most reservoirs have a pronounced plateau along which saturation rapidly increases. The pressure at 10% or 40% saturation gives a similar Pd.
  • Measured saturations required to create a continuous hydrocarbon filament range from 5–17% with an average of 10%.[1]

Alternatively, some workers define Pd as the pressure at the first inflection point of capillary curve.[3] Figure 2 shows the inferred Pd at both 10% saturation and at the inflection point.

Cores, cuttings, and low-permeability rocks

Samples for mercury injection laboratory analysis can include cores as well as cuttings. Measurements made from cuttings do not yield the same value as those from cores, so they require an empirical correction factor that ranges from 15–250 psi.[4]

Seals with low permeability and small pore throats may require longer equilibration times during mercury injection.[2]

Converting laboratory measurements

Since laboratory measurements of Pd are given in the air-mercury system rather than the oil-water or gas-water systems, we must convert from Pdm, using mercury, to Pdh, or hydrocarbons:

where:

  • γ = interfacial tension, dynes/cm
  • θ = contact angle or wettability, degrees

Displacement pressures measured in the air-mercury system are then converted to the hydrocarbon–water system at subsurface conditions. To convert, we must know the temperature, pressure, wettability, and coefficient of interfacial tension for the hydrocarbon phase. These parameters are commonly inferred from the composition, gas–oil ratio, and API gravity.[1] [2] For the air–mercury system, the wettability of mercury is 140° (cos 140 = 0.766). The coefficient of interfacial tension for mercury is 485 dynes/cm.[2]

See also

References

  1. 1.0 1.1 1.2 1.3 Schowalter, T. T., 1979, Mechanics of secondary hydrocarbon migration and entrapment: AAPG Bulletin, vol. 63, no. 5, p. 723–760.
  2. 2.0 2.1 2.2 2.3 Vavra, C. L., J. G. Kaldi, and R. M. Sneider, 1992, Geological applications of capillary pressure: a review: AAPG Bulletin, vol. 76, no. 6, p. 840–850.
  3. Katz, A. J., and A. H. Thompson, 1986, Quantitative prediction of permeability in porous rock: Physical Review Bulletin, vol. 34, p. 8179–8181., 10., 1103/PhysRevB., 34., 8179
  4. Sneider, R. M., and G. Bolger, 1993, Estimating seals from wireline logs of clastic seals and reservoir intervals, in J. Ebanks, J. Kaldi, and C. Vavra, eds., Seals and Traps: A Multidisciplinary Approach: AAPG Hedberg Research conference, unpublished abstract.

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